dc.contributor.author | Yalçın, Ergin | |
dc.contributor.author | Duyar, Halil | |
dc.contributor.author | Çakmaz, Deniz | |
dc.contributor.author | Sahin, Ertan | |
dc.contributor.author | Seferoğlu, Zeynel | |
dc.date.accessioned | 2020-05-24T15:32:04Z | |
dc.date.available | 2020-05-24T15:32:04Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Yalçin, E., Duyar, H., Çakmaz, D., Şahin, E., Seferoğlu, Z.
(2019). The synthesis of blue emitting 3-Amino-1-hetarylfluorenes and their unprecedented alkylated
derivatives. Tetrahedron, 75 (35), art. no. 130464.
https://doi.org/10.1016/j.tet.2019.130464 | |
dc.identifier.issn | 0040-4020 | |
dc.identifier.uri | https://doi.org/10.1016/j.tet.2019.130464 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12508/1196 | |
dc.description | WOS: 000485335600003 | en_US |
dc.description.abstract | Novel 3-Amino-1-hetarylfluorene derivatives have medicinal uses and challenging transformation in organic synthesis have been synthesized via decyanation process. Surprisingly, the alkylated compounds derived from 3-Amino-1-hetarylfluorenes were obtained via further nucleophilic substitution to the 9-C and 3-N positions of the fluorene ring because of the harsh reaction condition employed. The synthesized compounds were characterized by spectroscopic techniques as well as X-ray single crystal diffraction analysis. This new family of blue emitting fluorene derivatives have low to moderate quantum yields (the largest value of Phi(F) = 0.52 for compound 15). (C) 2019 Elsevier Ltd. All rights reserved. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [113Z704] | en_US |
dc.description.sponsorship | This research was supported by The Scientific and Technological Research Council of Turkey (TUBITAK) Grant no: 113Z704. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | en_US |
dc.relation.isversionof | 10.1016/j.tet.2019.130464 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 3-Amino-1-hetaryl-2,4-dicyanofluorenes | en_US |
dc.subject | 3-Amino-1-hetarylfluorene derivatives | |
dc.subject | Decyanation reaction | |
dc.subject | Fluorescent dyes | |
dc.subject | Blue emitting fluorenes | |
dc.subject.classification | Chemistry | |
dc.subject.classification | Organic | |
dc.subject.classification | Hydrogenation | Nitrobenzene Derivative | Nitro Compounds | |
dc.subject.other | Selective hydrogenation | |
dc.subject.other | Efficient synthesis | |
dc.subject.other | Fluorene | |
dc.subject.other | Arylidenemalonodinitriles | |
dc.subject.other | Nanoparticles | |
dc.subject.other | Reduction | |
dc.subject.other | Catalysts | |
dc.subject.other | Alcohols | |
dc.subject.other | Nitro | |
dc.subject.other | Alkylation | |
dc.subject.other | Carbon nuclear magnetic resonance | |
dc.subject.other | Chemical analysis | |
dc.subject.other | Chemical reaction | |
dc.subject.other | Fourier transform infrared spectroscopy | |
dc.subject.other | Nucleophilicity | |
dc.subject.other | Priority journal | |
dc.subject.other | Proton nuclear magnetic resonance | |
dc.subject.other | Quantum yield | |
dc.subject.other | Spectrofluorometry | |
dc.subject.other | Spectroscopy | |
dc.subject.other | Synthesis | |
dc.subject.other | Ultraviolet visible spectroscopy | |
dc.subject.other | X ray crystallography | |
dc.subject.other | X ray diffraction | |
dc.title | The synthesis of blue emitting 3-Amino-l-hetarylfluorenes and their unprecedented alkylated derivatives | en_US |
dc.type | article | en_US |
dc.relation.journal | Tetrahedron | en_US |
dc.contributor.department | Mühendislik ve Doğa Bilimleri Fakültesi -- Mühendislik Temel Bilimleri Bölümü | en_US |
dc.identifier.volume | 75 | en_US |
dc.identifier.issue | 35 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.contributor.isteauthor | Yalçın, Ergin | |
dc.relation.index | Web of Science - Scopus | |
dc.relation.index | Web of Science Core Collection - Science Citation Index Expanded | |
dc.relation.index | Web of Science Core Collection - Index Chemicus | |